Corrosion Properties in Sodium Chloride Solutions of Al–TiC Composites in situ Synthesized by HFIHF
Sherif, El-Sayed M. . 2015
Al–TiC nanocomposite materials have been prepared by a new in situ synthesizing technique. A mixture of aluminum, titanium, and graphite has been prepared using ball milling technique and then melted in a high frequency induction heat furnace (HFIHF) at different sintering temperatures, namely 900, 1100, and 1300 ° C. The effect of sintering temperature on the corrosion of the Al–TiC composite in 3.5% NaCl solutions was investigated using cyclic potentiodynamic polarization, chronoamperometric current-time, open-circuit potential, and electrochemical impedance spectroscopy measurements. The surface of the composites after their corrosion in the test solution was investigated using scanning electron microscopy and energy dispersive X-ray analyses. It has been found that all manufactured composites suffer uniform corrosion. All corrosion test techniques were consistent with each other and confirmed clearly that the corrosion resistance of Al composites increased according to their sintering temperature in the following order 900 > 1100 > 1300 ° C.
The high cost of Pt-based electrode materials limits the commercialization of fuel cells and their subsequent application in renewable energy production. It is thus necessary to develop economical…