المنشورات و المؤلفات
A new alternating chain compound consisting of gold(I) and silver(I) bridged by cyanides is reported. The Ag(I)
ion is functionalized by 2 triphenyl phosphane ligands, resulting in the formula [Au(C`N)2(PPh3)2Ag]n. The
compound has been prepared by...
Abstract We report here the synthesis of naked magnetic nanoparticles by using a facile method.
Magnetic nanoparticles were prepared by mixing and stirring two equivalents of iron(II) chloride
tetrahydrate with three equivalents of iron(III)...
The novel cationic complex [Ag14(C2tBu)12]2+ has been synthesized
by four reactions: reaction of [Ag(C2tBu)]n and
AgBF4 in acetone in a 6:1 mole ratio, that of HCCtBu and
AgBF4 in water in the absence of a base, treatment of
[AgC2tBu]n with HBF4 in...
Abstract: A conformational search of 5,12-dihydro-5,12-ethanonaphthacene-13-carbaldehyde
predicted the presence of twelve conformations. The geometry of the twelve conformations
established at the B3LYP/6-31G* level showed only six unique ones....
The gold complex i.e., [Au2(CºN)2P(Ph)2CH2P(Ph)2] has been successfully produced by three reactions, the reaction of polymeric gold
cyanide [Au(CN)]n with a suspension of bis(diphenylphosphino)methane (dppm), in acetone in a 2:1, pure ammonia (NH3...
a b s t r a c t
A series of three cyanide-bridged chain coordination compounds with the formulae [M(CN)2(PPh3)2Ag]n (M is Ag,
Cu or Au) is presented. The compounds have been prepared by roomtemperature reactions of triphenylphosphane
with the...
a b s t r a c t
Two new cyanido-bridged coinage metal compounds are presented. A novel hetero trinuclear Ag–Cu–Au
compound of formula [AgCuAu(CN)3(PPh3)5](H2O)2 1 is described with bridging cyanide ligands between
the metals, and terminal phosphane...
a b s t r a c t
Two new compounds containing the (acetylido)(cyanido)aurate(I) anion are reported. Their solid-state
structures with the monocation PPN, bis(triphenylphosphane)iminium, are reported as a product containing
a water molecule and an...
a b s t r a c t
Four new compounds containing the (chlorido)(2x)(cyanido)xargentate(I) anion (x = 2, 1.63, 1 and 0.5) are
reported. Their solid-state structures with the monocation PPN, bis(triphenylphosphane)iminium, are
described; in a few cases...
a b s t r a c t
Three new compounds containing the bis(triphenylphosphane)iminium cation (PPN+) with ClO4
−, BF4
− and
[AgCl2]− as counter anions have been synthesized and structurally characterized. The two derivatives with ClO4
−
and BF4
− were...