A novel and selective nitrite sensor based on non-covalent interaction of Schiff base copper complex [Cu(sal-ala)(phen)] with reduced graphene oxide (RGO) was developed by simple eco-friendly approach. The morphology of the prepared RGO/[Cu(sal-ala)(phen)] nanocomposite was characterized by scanning electron microscopy (SEM), ultraviolet visible spectroscopy (UV), electrochemical impedance spectroscopy (EIS), energy dispersive X-ray spectroscopy, X-ray diffraction studies and Fourier transform infrared spectroscopy (FT-IR).