Identified as potential materials for optoelectronic applications, the polymer/inorganic nanocomposites are actively studied. In this work, the effect of amorphous silica nanoparticles (NPs) content on the optical properties of Poly (9,9’-din-octylfluorenyl- 2.7-diyl) (PFO) thin films has been investigated. Different ratios of PFO/SiO2 NPs composites have been prepared using solution blending method. Then, the blends were spin-coated onto glass substrates at 2000 rpm for 30 s and subsequently dried at room temperature.