The Electron Paramagnetic Resonance (EPR) study of the iron ions are very important where these paramagnetic centres show several desired properties when doped in the host STO (SrTiO3) crystal. It leads to highly disordered local states, highly conductivity, change the STO from semiconductor to conductor, ferromagnetic, and ferroelectric transition at local symmetry low. This sample can be used in detectors, receivers, transistor, thin film and Non-Volatile Ferroelectric Random-Access Memories (NVFRAMs).