4-(5-{2-[5-(4-Cyanophenyl)-3-methylthiophen-2-yl]-3,3,4,4,5,5-hexafluorocyclopent-1-en-1-yl}-4-methylthiophen-2-yl)benzonitrile chloroform hemisolvate

The crystal structure of the title compound, C29H16F6N2S2-0.5 CHCl3, consists of molecules with disordered perfluorocyclopentene rings [occupancy ratio 0.685 (3):0.315 (3)] and close F...F contacts (in the range 2.45–2.73 Å) between molecules. The short contacts are associated with the disorder. The dihedral angle between thiophene rings is 57.44 (8)°. The 5-(4-cyanophenyl)-3-methyl-2-thienyl groups of adjacent molecules are parallel, leading to zigzag chains of molecules along [101].

Extending the Single Machine-Based Relaxation Scheme for the Job Shop Scheduling Problem

The contribution of this paper to the job shop related literature is twofold. First, we provide an efficient way forf solving the job shop scheduling problem with release dates, delivery times and delayed precedence constraints. It is shown that the latter problem is equivalent to a classical job shop with precedence constraints. Second, an effective extension of the standard single machine-based relaxation scheme is derived.

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اشترك ب KSU Faculty آر.إس.إس